also this song,
http://www.youtube.com/watch?v=ZovvOL0JgW4
Written by Barnes/Schon/Cain for the Freight Train Heart album, but not used. Ended up being recorded by The Rossington Band, with the Barnes vocal style being practically unchanged. No idea whether the Barnes demo still exists.
There were 2 cds with Jimmy Barnes. The first one, a reworking of Barnes' solo debut album Bodyswerve had Cain producing and was entitled For the Working Class Man. Designed to break Barnes in the US, about half the tracks from Bodyswerve were re-recorded, along with 5 "new" songs from various sources. The Cain-written Working Class Man,
http://www.youtube.com/watch?v=erSJGrpfnOI, was a HUGE hit in Barnes' home country of Australia, firmly established Jimmy Barnes as a successful solo singer after the breakup of Cold Chisel, and was probably the single biggest hit for Cain outside of Journey. Cain also contributed American Heartbeat to the album.
After the success, Cain and Barnes reteamed for the successor, Freight Train Heart, which would go on to be Barnes' biggest solo success. Neal Schon was brought in, along with Randy Jackson and a host of session players. The majority of the album was Barnes/Cain co-writing with some other people, and included one Barnes/Cain/Schon song in I Wanna Get Started With You,
http://www.youtube.com/watch?v=V0xCngWi-BU. A falling out between Barnes and Cain led to Barnes going back to Australia to re-record the lead vocals. Apparently, Schon played at least a few songs with Barnes, although I've never heard of a recording from these shows.
and this one, presumably written for Bad English.
http://www.youtube.com/watch?v=qW3QykpPWM0.
Recorded as a demo by Mark Free. Rerecorded as Cain solo for the Back to the Innocence album. There's also a John Waite version floating around somewhere also.